Glad to hear my question has gathered very much interesting answers! I haven't enough fantasy for imagine something interesting, so I will watch from the sidelines.
If I could meet Cave Johnson, I would... Ask for some combustible lemons. (I made one before. Strongly reccomend using battery acid and other volatile chems, freeze drying em, and putting it all In a lemon, but gunpowder from fireworks. Worked fine
A little update: "Presidente, please, while they may disagree with you, please stop sending armored divisions after every protest. Maybe... it would be cheaper and less bloody to fix healthcare?"
If i were to meet Lucio i would tell him to drop the beat. As for my second favorite character, Junkrat, probably something about explosives.