I tried using google about these little guys but, a witch just flew over my slime hut and this happened... Anyone know what is up with these little coal colored slimes?
From what I read from a previous case, the black slimes have a higher chance of dropping coal. (though I haven't experienced it personally, so I can't say for sure) You could try breeding them and killing them for a steady supply of coal.
It happened to me to a few days ago too, along with the above I tend to get diamonds often from them too http://images.akamai.steamusercontent.com/ugc/548682681773831955/F12EC3A6820FFA0DCF38140D6317C9125A77ABBB/